SUCCINIC ACID
|
PRODUCT
IDENTIFICATION
|
CAS
NO. |
110-15-6 |
|
EINECS
NO. |
203-740-4
|
FORMULA |
HOOCCH2CH2COOH |
MOL
WT. |
118.09 |
H.S.
CODE |
2917.19
|
TOXICITY
|
Oral
rat LD50: 2260 mg/kg |
SYNONYMS |
Butanedionic
acid; Amber acid; Butanedioic acid; |
Dihydrofumaric
acid; asuccin; 1,2-ethanedicarboxylic acid; wormwood;
wormwood acid; katasuccin; Asuccin; Bernsteinsaure (German);
Kyselina Jantarova (Czech); |
RAW
MATERIALS
|
|
CLASSIFICATION
|
|
GENERAL
DESCRIPTION
|
Succinic
Acid (Butanedioic Acid) is a dicarboxylic
acid of four carbon atoms. It occurs naturally in plant
and animal tissues. It plays a significant role
in intermediary metabolism (Krebs cycle) in the body. Krebs cycle (also called citric acid cycle; tricarboxylic acid cycle) is a
sequence process of enzymatic reaction which a two-carbon acetyl unit is
oxidized to carbon dioxide and water to provide energy in the form of
high-energy phosphate bonds. Succinic
acid is a colourless
crystalline solid with a melting point of 185 -187
C; soluble in water; slightly dissolved in ethanol,
ether, acetone and glycerine; not dissolved in benzene,
carbon sulfide, carbon tetrachloride and oil ether.
The common method of synthesis of succinic acid is the
catalytic hydrogenation of maleic acid or its anhydride.
Carboxylic acid can
yield
acyl halides, anhydrides, esters,
amides, and nitriles for the application of drug,
agriculture, and food products, and other industrial
uses.
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
Odorless
white crystals |
MELTING
POINT |
187
- 189 C |
BOILING
POINT |
235
C |
SPECIFIC
GRAVITY |
1.552 |
SOLUBILITY
IN WATER |
moderately
soluble
|
pH |
|
VAPOR
DENSITY |
3.04 |
AUTOIGNITION
|
630
C
|
NFPA
RATINGS |
Health:
2; Flammability: 1; Reactivity: 0 |
REFRACTIVE
INDEX
|
1.405 |
FLASH
POINT |
206
C
|
STABILITY |
Stable
under ordinary conditions |
APPLICATIONS
|
Flavoring
agent for food and beverages; Producing five heterocyclic
compounds, Intermediate for dyes, perfumes, lacquers,
photographic chemicals, alkyd resins, plasticizer, Metal
treatment chemical, vehicle water cooling systems and
coatings. Medicines of sedative, antispasmer, antiplegm,
antiphogistic, anrhoter, contraception and cancer-curing.
|
SALES
SPECIFICATION |
APPEARANCE
|
Colorless
to white crystalline power
|
PURITY
|
99.50%
min
|
FUMARIC
& MALEIC ACID |
0.1%
max
|
MOISTURE
|
0.5%
max
|
MELTING
POINT |
185
- 189 C
|
CHLORIDE
(Cl )
|
0.002%
max
|
IRON
(Fe )
|
0.002%
max
|
SULFATE
( SO4)
|
0.002%
max
|
ARSENIC
( As )
|
3ppm
max
|
HEAVY METAL (As Pb
)
|
10ppm
max
|
TRANSPORTATION |
PACKING |
25kgs
in bag |
HAZARD
CLASS |
|
UN
NO. |
|
GENERAL
DESCRIPTION OF DICARBOXYLIC ACID |
Dicarboxylic
acid is a compound containing two carboxylic acid, -COOH,
groups. Straight chain examples are shown in table. The
general formula is HOOC(CH2)nCOOH,
where oxalic acid's n is 0, n=1 for malonic acid, n=2 for succinic acid, n=3
for glutaric acid, and etc. In substitutive
nomenclature, their names are formed by adding -dioic'
as a suffix to the name of the parent compound. They
can yield two kinds of salts, as they contain two carboxyl
groups in its molecules. The range of carbon chain lengths is from 2, but the
longer than C 24 is very rare. The term long chain
refers to C 12 up to C 24 commonly. Carboxylic
acids have industrial application directly or indirectly
through acid halides, esters, salts, and anhydride forms,
polymerization, and etc. Dicarboxylic acids
can yield two kinds of salts
or esters, as they
contain two carboxyl groups in one molecule.
It is useful in a variety of industrial applications
include;
- Plasticizer for
polymers
- Biodegradable solvents and lubricants
- Engineering
plastics
- Epoxy
curing agent
- Adhesive
and powder coating
- Corrosion inhibitor
- Perfumery
and pharmaceutical
- Electrolyte
There are almost
infinite esters obtained from carboxylic
acids. Esters
are formed by removal of water from an acid and an alcohol. Carboxylic acid
esters are used as in a variety of direct and indirect applications. Lower chain
esters are used as flavouring base materials, plasticizers, solvent carriers and
coupling agents. Higher chain compounds are used as components in metalworking
fluids, surfactants, lubricants, detergents, oiling agents, emulsifiers, wetting
agents textile treatments and emollients, They are also used as intermediates
for the manufacture of a variety of target compounds. The almost infinite esters
provide a wide range of viscosity, specific gravity, vapor pressure, boiling
point, and other physical and chemical properties for the proper application
selections.
C
length (Straight)
|
Product
|
CAS
#
|
Melting
Point
|
Boiling
Point
|
C
2
|
Oxalic
Acid (Ethanedioic
Acid) |
144-62-7 |
189
- 191
C
|
Sublimes
|
C
3
|
Malonic
Acid (Propanedioic
Acid)
|
141-82-2 |
131 - 135
C |
Decomposes
|
C
4
|
Succinic
Acid (Butanedioic Acid)
|
110-15-6 |
185
- 190 C
|
235
C
|
C
5
|
Glutaric
Acid (Pentanedioic
Acid)
|
110-94-1 |
95
- 99
C
|
302
C
|
C
6
|
Adipic
Acid (Hexanedioic Acid)
|
124-04-9 |
151
- 153
C
|
265
C at 100 mmHg
|
C
7
|
Pimelic
Acid (Heptanedioic Acid)
|
111-16-0 |
105
- 106
C
|
212
C at 10 mmHg
|
C
8
|
Suberic
Acid (Octanedioic Acid)
|
505-48-6 |
143
- 144
C
|
230
C at 15 mmHg
|
C
9
|
Azelaic
Acid (Nonanedioic Acid)
|
123-99-9 |
100
- 103 C
|
237
C at 15 mmHg
|
C
10
|
Sebacic
Acid (Decanedioic Acid)
|
111-20-6 |
131
- 134
C
|
294
at 100 mmHg
|
C
11
|
Undecanedioic acid |
1852-04-6 |
109
- 110 C
|
|
C
12
|
Dodecanedioic acid |
693-23-2 |
128
- 129 C
|
245
C at 10 mmHg
|
C
13
|
Brassylic acid (Tridecanedioic acid) |
505-52-2 |
112
- 114 C
|
|
C
14
|
Tetradecanedioic acid |
821-38-5 |
126
- 128 C
|
|
C
15
|
Pentadecanedioic acid |
1460-18-0 |
|
|
C
16
|
Thapsic acid (Hexadecanedioic acid) |
505-54-4 |
124
- 126 C
|
|
C
18
|
Octadecanedioic
acid
|
871-70-5
|
|
|
|
|